Final answer:
Using Hess's law and given reactions, the enthalpy change for the reaction 6 Ge (s) + 9 H2 (g) → 3 Ge2H6 (l) is calculated to be 705.23 kJ.
Step-by-step explanation:
To calculate the enthalpy change (ΔH) for the reaction 6 Ge (s) + 9 H2 (g) → 3 Ge2H6 (l), we need to use Hess's law and manipulations of the given equations. First, we need to identify how many times each given equation must be used to obtain the desired reaction when added together. The first equation is used in its current form (× 3), the second equation is reversed and used (× 6), and the third equation is used (× 7).
Using Hess's law:
- 3 × Equation 1: 3(137.3 kJ/mol) = 411.9 kJ
- 6 × Equation 2 (reversed): 6(–247.8 kJ/mol) = -1486.8 kJ
- 7 × Equation 3: 7(455.8 kJ/mol) = 3190.6 kJ
Summing the enthalpy changes of the individual steps:
(411.9 kJ) + (-1486.8 kJ) + (3190.6 kJ) = 2115.7 kJ
We then divide this sum by the number of times the target reaction occurs, which is three:
× 3 Target Reaction: 2115.7 kJ / 3 = 705.23 kJ
Therefore, the enthalpy change for the reaction 6 Ge (s) + 9 H2 (g) → 3 Ge2H6 (l) is 705.23 kJ.