Final answer:
Cyanobacteria, which produce oxygen as a by-product of photosynthesis, appeared within one billion years of Earth's formation, leading to the oxygenation of the atmosphere.
Step-by-step explanation:
d. For the first two billion years of Earth's existence, the atmosphere had no molecular oxygen. Thus, the first organisms were anaerobic. Cyanobacteria which produce oxygen as a by-product of photosynthesis, leading to the oxygenation of the atmosphere, appeared within one billion years of Earth's formation. From these organisms evolved phototrophic organisms.