Final answer:
The critical temperature in a phase diagram is the highest temperature at which a substance can exist as a liquid.
Step-by-step explanation:
The critical temperature (Tc) in a phase diagram refers to the highest temperature at which a substance can exist as a liquid. Above the critical temperature, the molecules have too much kinetic energy for the intermolecular attractive forces to hold them together in a separate liquid phase, and instead, the substance forms a single phase that completely occupies the volume of the container. The critical temperature is a characteristic property of a substance and is influenced by the strength of intermolecular forces.