Final answer:
Approximately 18.4 liters of NH₃ (g) at 850°C and 5.00 atm are required to react with 1.00 mol O₂ in the first step of the industrial process for making nitric acid.
Step-by-step explanation:
To determine the number of liters of NH₃ (g) required to react with 1.00 mol O₂, we need to use the balanced chemical equation and convert the moles of NH₃ to liters using the ideal gas law.
- Balance the chemical equation: 4 NH₃ (g) + 5 O₂ (g) → 4 NO (g) + 6 H₂O (g)
- Convert the moles of NH₃ to moles of O₂ using the stoichiometric ratio: 4 moles NH₃ = 5 moles O₂
- Convert the moles of O₂ to liters using the ideal gas law: PV = nRT, where P = pressure, V = volume, n = number of moles, R = ideal gas constant, and T = temperature in Kelvin.
Let's assume the temperature is 850°C, which is 1123 K, and the pressure is 5.00 atm.
Using the ideal gas law equation, we can rearrange it to solve for volume (V): V = (nRT) / P
We know the number of moles of O₂ is 1.00 mol, R = 0.0821 L·atm/mol·K, and P = 5.00 atm. Substituting these values into the equation, we can calculate the volume of NH₃ (g) required.
V = (1.00 mol * 0.0821 L·atm/mol·K * 1123 K) / 5.00 atm = 18.4316 L
Therefore, approximately 18.4 liters of NH₃ (g) at 850°C and 5.00 atm are required to react with 1.00 mol O₂ in this reaction.