Final answer:
In the reaction 2 Na(s) + F₂(g) → 2 NaF(s), F₂ is the species that is reduced as its oxidation number goes from 0 to -1, becoming fluoride ions Fⁱ-.
Step-by-step explanation:
In the reaction 2 Na(s) + F₂(g) → 2 NaF(s), the species that is reduced is F₂. To determine which species is reduced, we need to look at the changes in oxidation numbers for the reactants. Sodium (Na) starts in its elemental form with an oxidation number of 0 and becomes Naⁱ+ in NaF, indicating that Na is oxidized. Fluorine (F₂) starts with an oxidation number of 0 in its molecular form and becomes Fⁱ- in NaF, indicating a reduction in oxidation number from 0 to -1. Hence, the reduction occurs with F₂, which gains electrons to become fluoride ions (Fⁱ-).