Final answer:
The unnecessary step is asking volunteers about their favorite dessert, as it does not help in determining the average daily caloric intake.
Step-by-step explanation:
The step in George's experimental procedure that is unnecessary for determining the average daily calorie consumption of the American diet is asking volunteers about their favorite dessert. This question does not contribute to calculating the caloric intake. The necessary steps include finding 100 volunteers to record their weekly food intake, collecting their records, calculating the total number of calories consumed during the week for each volunteer, and dividing each volunteer's total calorie count by seven to obtain the daily average, followed by averaging these daily calories across all participants.