Final answer:
The correct statistical scenario for evaluating the impact of the exercise program on workers' job satisfaction with 'before' and 'after' scores is the Paired t-test due to the paired nature of the data.
Step-by-step explanation:
The appropriate statistical scenario for the company assessing the impact of its exercise program on job satisfaction, with scores recorded before and after the program's implementation, is the Paired t-test. This is because the same group of workers is being measured twice, providing a set of paired data. Each worker has a 'before' and 'after' score, and the paired t-test will compare the means of these two related groups to see if there has been a significant change in job satisfaction.