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In a real gas, as the temperature decreases, it is possible to cause a liquid to form. How would the formation of a liquid affect the measurement of absolute zero using the methodology employed in this experiment?

A) It would underestimate absolute zero.
B) It would overestimate absolute zero.
C) It would not affect the measurement.
D) It would make the measurement impossible.

User Matthisk
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1 Answer

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Final answer:

When measuring absolute zero by observing the volume of a gas, if the gas liquefies before reaching absolute zero, this would lead to an underestimation of the temperature because the liquid's volume is larger than what the extrapolated volume of the gas would be at absolute zero. Option A is correct..

Step-by-step explanation:

In this experiment, as the temperature of a real gas is lowered, it may condense into a liquid before reaching absolute zero (0 K or -273.15°C), which is the temperature at which all molecular motion ceases. The formation of a liquid from a gas during the experiment would cause the volume of the substance to dramatically decrease, as a liquid has a significantly smaller volume than its gaseous form. Therefore, if a gas were to liquefy before reaching absolute zero, this would affect the measurement based on the volume-temperature relationship used in the experiment.

Given that the gas turns into a liquid before reaching absolute zero, the volume at this phase change will no longer approach zero in a manner directly proportional to temperature decreases. This suggests that the presence of a liquid phase would lead to an incorrect extrapolation when trying to determine absolute zero based on gas behavior. Hence, the correct answer to the student's question is A) It would underestimate absolute zero because the volume of the condensed liquid will be significantly greater than the volume the gas would have if it remained a gas all the way down to absolute zero.

User Sid Brooklyn
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