Final answer:
A buffer maintains the pH of a solution when an acid is added by having the added hydrogen ions react with the conjugate base in the buffer, resulting in a minimal change in pH.
Step-by-step explanation:
Buffers work by maintaining a relatively constant pH when a strong acid or base is added to a solution. This is because buffers consist of a weak acid and its conjugate base, or a weak base and its conjugate acid. When an acid is added to a buffer solution, the added hydrogen ions (H+) react with the conjugate base present in the buffer. For example, in an acetic acid-sodium acetate buffer, hydrogen ions would react with acetate ions to form more acetic acid molecules. This reaction shifts the equilibrium in such a way that the increase in hydronium ion concentration is minimized, and thus the pH remains relatively unchanged. Similarly, if a base is added, it reacts with the weak acid in the buffer to form water and the conjugate base, reducing the potential increase in pH.