Final answer:
The relationship between ∠3 and ∠6 is that they are corresponding angles and congruent when intersected by a transversal on two parallel lines.
Step-by-step explanation:
The relationship between ∠3 and ∠6 when lines L1 and L2 are parallel and ∠3 is ∠6 are corresponding angles and are congruent. Corresponding angles are those that are in the same relative position at each intersection where a transversal intersects two or more lines. Since lines L1 and L2 are parallel, ∠3 and ∠6 will have the same measure, making option B the correct answer: B) ∠3 and ∠6 are corresponding angles and are congruent.