Final answer:
The coefficient that should be placed in front of O₂ to properly balance the chemical equation is 8 (D).
Step-by-step explanation:
The balanced chemical equation for the reaction S₈ + O₂ → SO₂ is 2S₈ + 8O₂ → 8SO₂. Therefore, the coefficient that should be placed in front of O₂ isto properly balance the equation.