Final answer:
The correct standard cell notation for a galvanic cell involving silver and nickel is 'Ni(s) | Ni^2+(aq) || Ag+(aq) | Ag(s)', which corresponds to the cell configuration where nickel undergoes oxidation and silver undergoes reduction.
Step-by-step explanation:
The standard cell notation for a galvanic cell represents the oxidation and reduction half-cells, separated by a double line (||) which represents a salt bridge. Each half-cell is represented by the phase-bounded electrode (solid) followed by the electrolyte (aqueous solution), separated by a single line (|).
In the case of a galvanic cell made with silver (Ag) and nickel (Ni), we have the following cell reactions:
Combining these half-cell reactions into a standard cell notation, and considering the flow from anode to cathode, we would have:
Ni(s) | Ni2+(aq) || Ag+(aq) | Ag(s)
Therefore, the correct standard cell notation of this galvanic cell is option D: Ni(s) | Ni2+(aq) || Ag+(aq) | Ag(s).