The results suggest that nitrogen and oxygen in these samples obey the Law of Definite Proportions
Here is why:
The Law of Multiple Proportions states that when two elements form more than one compound, the masses of one element that combine with a fixed mass of the other element are in the ratio of small whole numbers.
To determine if nitrogen and oxygen in these samples obey the Law of Multiple Proportions, we need to examine the ratios of the volumes of oxygen (O) to nitrogen (N) for each sample.
- Sample 1:

- Sample 2:

- Sample 3:

The ratios are not close to simple whole numbers, indicating that the Law of Multiple Proportions is not followed.
Instead, the results suggest that nitrogen and oxygen in these samples obey the Law of Definite Proportions, as the ratios are not variable and are consistent within each sample.