Final answer:
Initially, the solution of calcium fluoride in water was unsaturated, but as solids began to settle, it became saturated, confirming the presence of both F- and Ca^2+ ions in the solution.
Step-by-step explanation:
When a certain mass of calcium fluoride is added to water and the solution becomes cloudy before clearing and allowing solid particles to sink, we can interpret the outcomes related to saturation. Initially, the solution could have been unsaturated (a) if the calcium fluoride (CaF2) was initially dissolving. Eventually, as solids begin to settle at the bottom, it suggests that the solution reached its maximum capacity to hold solute, becoming saturated (d). We can confirm the presence of F− ions (c) in solution because CaF2 dissociates to form Ca^2+ and F− ions. Similarly, the presence of Ca^2+ ions (e) is confirmed by the same dissociation process. A supersaturated solution (b) is not a likely scenario since no conditions were described to create such a state (such as lowering the temperature after dissolving excess solute).