Final answer:
Using the Combined Gas Law and converting temperatures to Kelvin, the volume of the gas at 60 kPa and 27°C is calculated as 7 L, matching option (d).
Step-by-step explanation:
A gas collected at 7°C and 140 kPa with a volume of 4 L needs to have its volume calculated at 60 kPa and 27°C. To accomplish this, we can use the Combined Gas Law which states that the ratio of the product of pressure and volume to the temperature is constant for a fixed amount of gas, thus:
P1 · V1 / T1 = P2 · V2 / T2
First, we need to convert temperatures to Kelvin by adding 273.15:
T1 = 7 + 273.15 = 280.15 K
T2 = 27 + 273.15 = 300.15 K
Next, we plug our known values into the Combined Gas Law and solve for V2:
(140 kPa · 4 L) / 280.15 K = (60 kPa · V2) / 300.15 K
V2 = (140 kPa · 4 L · 300.15 K) / (60 kPa · 280.15 K)
V2 = 7 L
The volume of the gas at 60 kPa and 27°C is thus 7 L, which corresponds to option (d).