Final answer:
The energy from ATP is released during the hydrolysis process, where a water molecule is added to ATP to form ADP and Pi.
Step-by-step explanation:
In the context of cellular energy transfer, the energy from ATP is released during the hydrolysis of ATP. This process involves the addition of a water molecule, breaking the high-energy phosphate bonds as shown in the equation ATP + H₂O → ADP + Pi + energy. The energy is released when the terminal phosphate group is removed from ATP to form adenosine diphosphate (ADP) and inorganic phosphate (Pi).