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Each of the following compounds possesses a plane of symme- try. Find the plane of symmetry in each compound. In some cases, you will need to rotate a single bond to place the molecule into a conforma- tion where you can more readily see the plane of symmetry.

User WhiteMist
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Final answer:

The question asks to find the plane of symmetry in molecules that may have conformational isomers or stereoisomers due to rotations around single bonds or fixed spatial arrangements, respectively, such as in ethene with its planar double bonds and tetrahedral single bonds.

Step-by-step explanation:

The question pertains to finding the plane of symmetry in chemical compounds, particularly those that exhibit certain types of isomerism resulting from different spatial arrangements. When looking for planes of symmetry, one must consider the three-dimensional structure of molecules. In conformational isomers, the different spatial arrangements are due to rotation around single (sigma) bonds, allowing for various conformations. In contrast, stereoisomers cannot be inter-converted without breaking bonds, as they have distinct three-dimensional arrangements that are non-superimposable, even though they have the same connectivity.

For example, a molecule like ethene, which has a double bond, is locked in a planar configuration and cannot rotate, leading to potential cis and trans geometric isomers, each with a different plane of symmetry. In a tetrahedral arrangement, where carbon forms single bonds, the molecule is capable of rotation, which may temporarily obscure the plane of symmetry until the molecule is rotated into a particular conformation that reveals it.

In the context of the question, one would need to sometimes rotate single bonds to orient the molecule in such a way that the plane of symmetry becomes apparent. This exercise highlights the concept of molecular polarity, geometric isomers, and the properties and behaviors of sigma and pi bonds.

User Mpellegr
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