Final answer:
To find the volume of oxygen gas needed to react with 48.7 g of MoS2, calculate the moles of MoS2 and then use the balanced equation and ideal gas law to find the required volume, which comes out to approximately 26.2 liters.
Step-by-step explanation:
To determine the volume of O2 gas that would be needed to react with 48.7 g of MoS2, first, we need to balance the chemical equation:
2 MoS2(s) + 7 O2(g) → 2 MoO3(s) + 4 SO2(g)
Next, we need to calculate the moles of MoS2 reacting by using its molar mass:
Molar mass of MoS2 = 95.96 g/mol (Mo) + 2 * 32.07 g/mol (S) = 160.10 g/mol
Moles of MoS2 = 48.7 g / 160.10 g/mol ≈ 0.304 moles
The stoichiometry of the balanced equation shows that 2 moles of MoS2 react with 7 moles of O2. Therefore, we have:
0.304 moles MoS2 * (7 moles O2 / 2 moles MoS2) = 1.06 moles O2
At 27.5°C and 1 atm, we use the ideal gas law to find the volume of 1 mole of O2:
V = nRT / P
Where:
- n = number of moles of O2
- R = 0.0821 L atm/mol K, ideal gas constant
- T = temperature in Kelvin = 27.5°C + 273.15 = 300.65 K
- P = pressure in atm = 1 atm
Therefore, the volume needed for 1.06 moles of O2 is:
V = (1.06 moles) * (0.0821 L atm/mol K) * (300.65 K) / (1 atm) ≈ 26.2 L
So, about 26.2 liters of O2 gas is needed to react with 48.7 g of MoS2 under the given conditions.