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The following radial probability diagram could theoretically represent which orbital(s)?

1) s orbital
2) p orbital
3) d orbital
4) f orbital

1 Answer

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Final answer:

The radial probability diagram could represent an s orbital, which is spherically symmetrical with a radial probability that only depends on the distance from the nucleus. S orbitals correspond to the azimuthal quantum number l = 0, with each increase in n providing additional nodes in the radial probability distribution.

Step-by-step explanation:

The radial probability diagram mentioned could theoretically represent an s orbital, as s orbitals are characterized by being spherically symmetrical with no angular dependence. In the context of quantum mechanics and atomic theory, the quantum number l (azimuthal or angular momentum quantum number) defines the shape of an orbital, with l = 0 being s orbitals, which are spherical. Each higher value of l corresponds to a different type of orbital: l = 1 for p orbitals, l = 2 for d orbitals, and l = 3 for f orbitals, with each having increasingly complex shapes and angular dependencies. Since s orbitals are spherically symmetrical, the electron probability density for s orbitals is only dependent on the radius from the nucleus and does not vary with angle, leading to the signature radial probability distributions as shown in the examples for the 1s, 2s, and 3s orbitals. As the principal quantum number n increases, the most probable radius for finding an electron also increases, but there are additional minima in the radial probability due to the presence of nodes, which are regions where there is zero electron probability. The number of nodes is related to the principal quantum number as well, with a total of n - l - 1 nodes for a given orbital.

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