Final answer:
Statements a and b are correct: The reaction of an aldehyde with Collins' reagent produces a primary alcohol. The reaction of a carboxylic acid with thionyl chloride allows the formation of an alkyl chloride.
Step-by-step explanation:
A. The reaction of an aldehyde with Collins' reagent produces a primary alcohol.
B. The reaction of a carboxylic acid with thionyl chloride allows the formation of an alkyl chloride.
C. The acid hydrolysis of a nitrile group in a molecule gives the formation of an aldehyde.
D. Methyl ketones give a positive haloform test.
Therefore, the correct statements are:
a. The reaction of an aldehyde with Collins' reagent produces a primary alcohol.
b. The reaction of a carboxylic acid with thionyl chloride allows the formation of an alkyl chloride.