Final answer:
To sketch a potential energy diagram for an endothermic reaction (AB → B + A, ΔH = +66.4kJ), one must draw the reaction progress and potential energy axes, show the reactants at a lower energy level than the products, indicate the higher activation energy peak, and label the enthalpy change (ΔH) reflecting the energy absorbed.
Step-by-step explanation:
To sketch a potential energy diagram for the reaction AB → B + A with a ΔH of +66.4kJ, we need to illustrate the energy changes throughout the reaction. Below are the steps and labeled components:
- Begin by drawing the horizontal axis, representing the reaction progress, and the vertical axis, indicating the potential energy of the system.
- Mark the initial energy level of the reactants, AB, on the vertical axis.
- Since the ΔH is positive, this means the reaction is endothermic; thus, the products will have a higher energy level than the reactants. Draw a second line above the reactants to represent the products, indicating an increase in potential energy.
- The peak of the diagram represents the activation energy (Ea) needed for the reaction to proceed. The specific Ea value is not given, but it should be drawn as a peak between the reactants and products.
- The enthalpy change, ΔH, of the reaction should be labeled as the difference in energy between the reactants and products.
As a result, the potential energy diagram will show an upward curve from the reactants to the transition state, then descending toward the products, reflecting the endothermic nature of the reaction.