Final answer:
The reading on the thermometer when the first few drops of liquid appear is likely to be around 70-75°C. The liquid that appears first on the thermometer is hexane.
Step-by-step explanation:
(i) The reading on the thermometer when the first few drops of liquid appear will be the boiling point of the liquid. Since hexane has a boiling point of 69°C and heptane has a boiling point of 98°C, the reading on the thermometer will be between these two values, closer to 69°C. So, the reading on the thermometer is likely to be around 70-75°C.
(ii) The liquid that appears first will be hexane, as it has a lower boiling point than heptane. Therefore, the liquid that appears first on the thermometer is hexane.