Final answer:
A galvanic cell must have a cell potential (Ecell) greater than zero for spontaneous reactions. In a galvanic cell, the value of Ecell must be greater than 0 for a spontaneous reaction with a negative value of ΔG. This is because a positive cell potential indicates a spontaneous reaction. Therefore, for a spontaneous reaction with a negative value of ΔG, the Ecell of a galvanic cell must be greater than 0.
Step-by-step explanation:
The question relates to the relationship between cell potential (Ecell) and spontaneity of electrochemical reactions in galvanic cells. By definition, for a reaction to be spontaneous, the Gibbs free energy change (delta G) must be less than zero (delta G correlates with a positive cell potential (Ecell < 0), which is a requirement for a galvanic cell to function. Therefore, the correct answer is that a galvanic cell must have an Ecell > 0 to ensure the overall reaction will occur spontaneously.