Final answer:
The chemist should pour out 175 mL of the barium chlorate stock solution.
Step-by-step explanation:
To calculate the volume of the barium chlorate stock solution that the chemist should pour out, we can use the dilution equation:
(stock concentration) x (stock volume) = (final concentration) x (final volume)
In this case, the stock concentration is 0.190 mol/L, the final concentration is 0.095 mol/L (converted from 95.0 mM), and the final volume is 350 mL. Rearranging the equation, we can find the stock volume:
(stock volume) = (final concentration) x (final volume) / (stock concentration)
Substituting the values, we get:
(stock volume) = (0.095 mol/L) x (0.350 L) / (0.190 mol/L) = 0.175 L = 175 mL