Final answer:
The CISO should be highly concerned about a security vulnerability on the website that could expose the new accounting service, considering previous incidents where breaches resulted in massive data exposure. Security should be prioritized over capacity planning to protect critical services.
Step-by-step explanation:
The Chief Information Security Officer (CISO) should be most concerned about the potential for a security vulnerability on the enterprise's website which could expose the accounting service to risk. When an enterprise experiences rapid growth, it is crucial to maintain the integrity and security of its computing resources. Hosting a new accounting service on the same virtual platform as the company's website could lead to a situation where a compromise of one service (e.g., the website) could directly impact the security of the other (e.g., the accounting service). The recent breaches in retailers and financial institutions have shown that such security vulnerabilities can result in significant exposure of personal information to identity theft and other cyber threats.
It is important that the Chief Technology Officer (CTO) and CISO work together to ensure that the technology department's resources are allocated in a way that does not compromise security. While capacity planning and budget constraints are also critical issues that need addressing, the immediate concern from a security standpoint is to ensure that critical services like accounting are insulated from potential breaches, thus maintaining the company's data integrity and customer trust.