Final answer:
Elements can be identified by their electron configurations, which are unique to each neutral atom. Ions, however, have altered configurations due to electron gain or loss, adhering to the octet rule, making them less distinct and harder to identify solely by their configurations.
Step-by-step explanation:
An element can be identified by its electron configuration because it reflects the unique arrangement of electrons in its neutral state. However, when an atom forms an ion by losing or gaining electrons, this alters the original electron configuration.
For instance, main group elements lose electrons that were added last, while transition metals lose their highest ns electrons first. When an element becomes an ion, it tries to reach a stable state known as the octet rule, which involves having eight electrons in the valence shell like the noble gases. This makes predicting the resultant ion's electron configuration more complex, potentially leading to multiple ions with similar configurations, so identifying an element based solely on the ion's electron configuration can be difficult.