Final answer:
Rust forming on a bar of pure iron is a chemical change, evidenced by the creation of iron oxide, a new substance different from pure iron, also known as corrosion.
Step-by-step explanation:
The observation that rust is forming on a bar of pure iron provides evidence that a chemical change is occurring. The correct option to indicate that a chemical change has occurred is: 'The rust is a new substance that is not pure iron.' This is because rust, which is iron oxide, has different properties from those of pure iron. This formation of rust is a process known as corrosion, which is a common term describing the combination of iron with oxygen to form iron oxide. Corrosion, specifically the rusting of iron, is a slow chemical process that releases energy much like combustion but at a rate that is usually not perceptible to the human senses.