Final answer:
The polar character of water molecules explains its large dielectric constant, and the permanent dipole moment per water molecule can be calculated using the given information.
Step-by-step explanation:
The polar character of water molecules helps to explain water's relatively large dielectric constant. Water is a polar molecule, with the oxygen end slightly negative and the hydrogen end slightly positive. This polarity allows water molecules to easily align along an external electric field, resulting in a large dielectric constant.
The permanent dipole moment (p₀) per water molecule can be calculated using the formula p₀ = M/m * sqrt(ε₀/εᵣ), where M is the molecular mass, m is the Avogadro's number, ε₀ is the vacuum permittivity, and εᵣ is the relative permittivity. Substituting the given values, p₀ can be calculated.