Final answer:
In DNA, adenine (A) pairs with thymine (T), and cytosine (C) pairs with guanine (G), following the base complementarity principle and maintaining the DNA's double helix structure through hydrogen bonds.
Step-by-step explanation:
The correct pairing relationships in DNA, which adhere to the concept of base complementarity, are that adenine (A) pairs with thymine (T) and cytosine (C) pairs with guanine (G). This pairing is due to hydrogen bonding that occurs only between a specific purine and a specific pyrimidine, ensuring the integrity and uniform width of the DNA double helix. Adenine and thymine form two hydrogen bonds between them, whereas cytosine and guanine form three hydrogen bonds.