Final answer:
If the redox potential of pC (plastocyanin) were altered to be more negative than the redox potential of cytochrome b6-f, NADPH production would halt since pC would no longer accept electrons from the cytochrome b6-f complex, blocking the electron transport chain.
Step-by-step explanation:
If the redox potential of pC (plastocyanin) were altered to be more negative than the redox potential of cytochrome b6-f, NADPH production would halt since pC would no longer accept electrons from the cytochrome b6-f complex, blocking the electron transport chain. This means that the flow of electrons from photosystem II to photosystem I would be disrupted, preventing the reduction of NADP+ to NADPH. As a result, the production of NADPH, which is important for the synthesis of glucose in the Calvin cycle, would be significantly reduced or completely stopped.