Final answer:
The initial source of electrons for the chloroplast electron transport chain is photosystem II (PSII).
Step-by-step explanation:
When photons strike photosystem II (PSII), pigments pass the light energy to chlorophyll molecules that excite electrons, which are then passed to the electron transport chain. The cytochrome complex transfers protons across the thylakoid membrane and transfers electrons from PSII to photosystem I (PSI). The products of the light-dependent reaction are used to power the Calvin cycle to produce glucose.