Final answer:
Phospholipids become arranged with their hydrophobic tails facing each other and their hydrophilic heads facing out, forming a lipid bilayer.
Step-by-step explanation:
The amphipathic nature of phospholipids is vital to the structure of a plasma membrane because, in water, phospholipids automatically become arranged with their hydrophobic tails facing each other and their hydrophilic heads facing out. In this way, they form a lipid bilayer—a barrier composed of a double layer of phospholipids that separates the water and other materials on one side from the water and other materials on the other side.