Answer
Empirical formula = C₁H₂
Molecular formula = C₄H₈
Step-by-step explanation
Given:
Total mass of sample = 0.6481 g
Mass of C = 0.5555 g
Mass of H = (0.64881 - 0.5555) g = 0.0926 g
Formula weight = 57
What to find:
The empirical and molecular formulas of the compound.
Step-by-step solution:
Step 1: Divide the mass of each element by their atomic mass:
Mole of C = 0.5555g/12.01 g/mol = 0.0463 mol
Mole of H = 0.0926 g/1.008 g/mol = 0.0919 mol
Step 2: Divide each mole by the smallest mole (mole ratio).
C = 0.0463/0.0463 = 1
H = 0.0919/0.0463 = 2
Step 3: Write the Empirical formula of the compound using the mole ratio in step 2.
Empirical formula = C₁H₂
Step 4: Determine the molecular formula of the compound using the empirical formula and the formula weight.
(Molecular formula) = (Empirical formula)ₙ
(57) = (C₁H₂)ₙ
57 = (1 x 12.01 + 2 x 1.008)ₙ
57 = (12.01 + 2.016)ₙ
57 = (14.026)ₙ
n = 57/14.026
n = 4
Molecular formula = (C₁H₂)₄ = C₄H₈
Therefore, the molecular formula = C₄H₈