Final answer:
Na₂CO₃ will increase the solubility of AgCO₃ in the saturated solution.
Step-by-step explanation:
When a substance is added to a saturated solution of AgCO₃, it can increase the solubility of AgCO₃ in the solution. Among the options given, the substance that will increase the solubility of AgCO₃ is Na₂CO₃ (option a).