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How to calculate number of ato s from empirical formula

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Final answer:

To find the number of atoms based on an empirical formula, calculate the empirical formula mass, divide the molecular mass by this value to find a multiplication factor (n), then multiply each subscript in the empirical formula by n to get the molecular formula.

Step-by-step explanation:

To calculate the number of atoms from an empirical formula, you must first understand the relationship between the empirical and molecular formulas. The empirical formula provides the simplest whole-number ratio of atoms in a compound, whereas the molecular formula gives the actual number of atoms of each element in a molecule of the compound. Here is how you can find the number of atoms using the empirical formula and the molar mass of the compound:

  1. Calculate the empirical formula mass (EFM), which is the sum of the average atomic masses for all atoms represented in the empirical formula.
  2. Divide the molar mass of the compound by the empirical formula mass. The result is a whole number or very close to it, which is the multiplier (n).
  3. Multiply the subscripts in the empirical formula by n to get the molecular formula, and thus the actual number of atoms of each element.

For example, if a compound's empirical formula is CH₂O and its molecular mass is 180 amu, you would first find the EFM (30 amu) and then divide the molecular mass by the EFM (180 amu / 30 amu = 6), which tells you the molecular formula contains six times the atoms in the empirical formula (C₆H₁₂O₆).

User Alexander Ulitin
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