Final answer:
The sampling method used in the given scenario is Cluster Sampling, where all individuals in selected clusters are surveyed.
Step-by-step explanation:
The type of sampling method being employed in the example where everyone at 6 selected Chili's locations are offered to try a new dessert for free on one weekend is Cluster Sampling. This sampling method involves dividing the population into clusters (in this case, the different Chili's locations in the metro-Atlanta area) and then selecting a whole cluster (or clusters) to include in the sample. The entire population within the selected clusters is surveyed, which distinguishes it from other methods like stratified sampling where only a few individuals from each stratum would be chosen.