Final answer:
The electron configuration of Fe²⁺ cation is 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁶.
Step-by-step explanation:
The electron configuration of Fe²⁺ cation is: 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁶. When Fe²⁺ loses two electrons, they are removed from the 4s orbital first, followed by removing electrons from the 3d orbital.