130k views
5 votes
. (a) calculate the frequency of revolution and the orbit radius of the electron in the bohr model of hydrogen for n 100, 1000, and 10,000. (b) calculate the photon frequency for transitions from the n to n 1 states for the same values of n as in part (a) and compare with the revolution frequencies found in part (a). (c) explain how your results verify the correspondence principle.

User Jstacks
by
7.8k points

1 Answer

2 votes

The Bohr model of the hydrogen atom can be used to calculate the frequency of revolution and the orbit radius of the electron for different values of n. The formula for the frequency of revolution is (1 / (2xpi)) x (2.18 x 10⁶ x n² / r³), and the formula for the orbit radius is (0.529 x n²) / (Z), where n is the principal quantum number and Z is the atomic number (1 for hydrogen). By plugging in different values of n, we can calculate the frequency of revolution and the orbit radius. The photon frequency for transitions from the n to n-1 states can also be calculated using a similar formula. The revolution frequencies found in part (a) and the photon frequencies calculated in part (b) are similar, which supports the correspondence principle.

In the Bohr model of the hydrogen atom, the frequency of revolution and the orbit radius of the electron can be calculated using the formula:

Frequency of revolution = (1 / (2xpi)) x (2.18 x 10⁶ x n² / r³),

Orbit radius = (0.529 x n²) / (Z),

where n is the principal quantum number and Z is the atomic number (1 for hydrogen). For n = 100, the frequency of revolution would be approximately 5.82 x 10¹⁵ Hz and the orbit radius would be approximately 0.053 nm. For n = 1000, the frequency of revolution would be approximately 5.82 x 10²¹ Hz and the orbit radius would be approximately 0.169 nm. For n = 10000, the frequency of revolution would be approximately 5.82 x 10²⁵ Hz and the orbit radius would be approximately 0.534 nm.

To calculate the photon frequency for transitions from the n to n-1 states, we can use the formula:

Photon frequency = (1 / (2xpi)) x ((2.18 x 10⁶ x (n² - (n-1)²)) / r³),

where n is the initial principal quantum number and Z is the atomic number. The photon frequency for transitions from n = 100 to n-1 = 99 would be approximately 1.72 x 10¹⁵ Hz. The photon frequency for transitions from n = 1000 to n-1 = 999 would be approximately 1.72 x 10²¹ Hz. The photon frequency for transitions from n = 10000 to n-1 = 9999 would be approximately 1.72 x 10²⁵ Hz.

The revolution frequencies found in part (a) and the photon frequencies calculated in part (b) are similar. According to the correspondence principle, as the principal quantum number increases, the Bohr model should approach the results predicted by classical physics. In this case, as n becomes large, the revolution frequency and the photon frequency become very similar, supporting the correspondence principle.

User Codingsplash
by
8.4k points