Final answer:
The minimum number of moles of AgNO3 that must be added to precipitate all of the Cl- ions is 0.20 mol.
Step-by-step explanation:
To precipitate all of the Cl- ions as AgCl(s), we need to determine the limiting reactant between NaCl and CaCl2. The number of moles of Cl- ions in 0.10 mol of NaCl is 0.10 mol, while the number of moles of Cl- ions in 0.10 mol of CaCl2 is 0.20 mol (since CaCl2 has two Cl- ions per formula unit). Therefore, the minimum number of moles of AgNO3 that must be added to the solution to precipitate all of the Cl- ions as AgCl(s) is 0.20 mol.