Final answer:
The average atomic mass of chlorine is calculated using the masses and relative abundances of its isotopes, resulting in an atomic mass of approximately 35.46 amu.
Step-by-step explanation:
To calculate the atomic mass of chlorine, considering its isotopes chlorine-35 and chlorine-37, we need to take their masses and relative abundances into account. The calculation is as follows:
For chlorine-35: atomic mass = 34.969 amu and percent abundance = 75.77%
For chlorine-37: atomic mass = 36.966 amu and percent abundance = 24.23%
We multiply each isotope's mass by its relative abundance (in decimal form) and sum the results to get the average atomic mass of chlorine:
(0.7577 × 34.969 amu) + (0.2423 × 36.966 amu) = 26.50 + 8.96 = 35.46 amu
Therefore, the average atomic mass of chlorine is approximately 35.46 amu, applying the rules of significant figures.