There are 13 spade cards in a regular deck of 52 cards.
I would say the expected value of pulling a spade card is 13/52 = .25 then multiply by 100 to get 25%.
Then the expected value of not pulling a spade would be the remaining value.
52 - 13 = 39 (non-spade cards)
39/52 = .75 multiply by 100, 75%
Pull a spade : 25%
Not pull a spade : 75%