Dinitrogen pentaoxide ===> nitrogen + oxygen
Dinitrogen pentaoxide = N2O5
Nitrogen (remember diatomic) = N2
Oxygen (remember diatomic) = O2
The reaction:
N2O5 ===> N2 + O2
To balance, we must have the same number of atoms on both sides.
So, you must add some numbers in front of each molecule.
Answer: 2 N2O5 ===> 2 N2 + 5 O2 (the balanced reaction)