Final answer:
Chemical weathering affects stone buildings through reactions that occur when acid rain and pollutants come into contact with limestone and marble, which are composed of calcium carbonate. These reactions lead to dissolution of the material, resulting in structural damage and loss of societal value.
Step-by-step explanation:
Chemical weathering plays a significant role in the degradation of stone buildings, including structures made from limestone and marble. This process is similar to the bubbling observed when vinegar reacts with limestone, signifying an acid-base reaction. In particular, acid rain, which contains strong acids like sulfuric acid, reacts with the calcium carbonate (CaCO3) that makes up limestone and marble. This reaction produces calcium sulfate (CaSO4), water (H2O), and carbon dioxide (CO2), as shown in the reaction:
CaCO3(s) + H₂SO₄ (aq) → CaSO₄(s) + H₂O(l) + CO₂(g)
Calcium sulfate is sparingly soluble, leading to the dissolution of the marble or limestone over time. This degradation process is exacerbated by pollutants like sulfur dioxide, which can accelerate weathering as concentrations of air pollutants increase, leading to more rapid deterioration of the stone.
Such chemical weathering reduces the structural integrity and societal value of stone buildings and cultural objects, causing concerns for the preservation of historical and cultural heritage.