Final answer:
The molar solubility of calcium carbonate is 2.06 x 10^-3 M, and the Ksp of calcium carbonate is 1.74 x 10^-8 M.
Step-by-step explanation:
The Ksp is the solubility product constant, which represents the equilibrium between a solid compound and its ions in a saturated solution. To calculate the Ksp of calcium carbonate, we need to set up an ICE (initial, change, equilibrium) table.
- CaCO3(s) → Ca2+(aq) + CO32-(aq)
- Initial concentration: 0 M
- Change in concentration: +x M (assuming the molar solubility of CaCO3 is x)
- Equilibrium concentration: x M for both Ca2+ and CO32-
Using the given concentration of 4.24 x 10-5 M, we can plug in the values to the Ksp expression:
Ksp = [Ca2+][CO32-]
Ksp = (x)(x) = x^2
Substituting the given concentration, we have:
4.24 x 10-5 = x^2
To solve for x, we take the square root of both sides:
x = √(4.24 x 10-5) = 2.06 x 10-3
Since we're asked to round to 3 significant figures, the molar solubility of CaCO3 is 2.06 x 10-3 M. Therefore, the Ksp of calcium carbonate is 4.24 x 10-5 M x 4.24 x 10-5 M = 1.74 x 10-8.