Final answer:
The reaction that will result in a reduced total pressure at constant temperature in a rigid reaction vessel is 2 N₂O(g) → 2 N₂(g) + O₂(g).
Step-by-step explanation:
In a reaction vessel, the total pressure is determined by the number of gas moles present. According to the ideal gas law, PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature.
To reduce the total pressure at constant temperature, the number of moles of gas needs to decrease. Looking at the given reactions, the following reaction will result in a reduced total pressure: 2 N₂O(g) → 2 N₂(g) + O₂(g).
This reaction involves a decrease in the number of moles of gas by converting 2 moles of N₂O to 2 moles of N₂ and 1 mole of O₂. This reduction in gas moles will lead to a reduced total pressure in the reaction vessel.
Learn more about Pressure reduction in a reaction vessel