Answer:
21.4 L
Step-by-step explanation:
You want the volume of a balloon at -31 °C if it is 24.9 L at 8 °C at the same pressure.
Volume
Volume the volume of the gas in the balloon is proportional to the absolute temperature, other things remaining the same.
V2/V1 = T2/T1
V2 = V2·T2/T1 = (24.9 L)(-31 +273.15)/(8 +273.15) ≈ 21.4 L
The new volume of the balloon is about 21.4 liters.
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Additional comment
Adding 273.15 to the temperature in °C converts it to a Kelvin temperature, referenced to absolute zero.