Final answer:
When Na2SO4(aq) and Ba(NO3)2(aq) are mixed, precipitation reaction occurs and BaSO4(s) is formed.
Step-by-step explanation:
A precipitation reaction occurs when two aqueous solutions react to form an insoluble solid called a precipitate. To determine if a precipitation reaction will occur, we can refer to the solubility guidelines. In this case, we need to consider the possible pairings of reactants. From the given options, the pair that will result in a precipitation reaction is Na2SO4(aq) and Ba(NO3)2(aq). When these reactants are mixed, a precipitate of BaSO4(s) will form. The balanced net ionic equation for this reaction is Ba^2+(aq) + SO4^2-(aq) -> BaSO4(s).