Answer:- When they are placed in series.
When multiple emf sources are connected in series then the net or total emf is equal to the sum of their individual emfs .
Say if we have cells of emfs
,
,
,
. . . .

Then the net emf is ,

Additional information:-
If the emfs of n cells are equal and they are connected in series then the net emf is given by ,

where ,
= emf of a single cell .
Also , when n cells of emfs
and
. . . . .
and internal resistances
,
. . . . .
respectively are connected in parallel then the net emf is given by,

Again suppose if we make a parallel arrangement of cells each having same emf then the net emf remains same that is equal to the emf of individual cell ( Why ? You can try yourself by using the above formula )
and we are done!