Final answer:
To find the value of k for the zero-order reaction a → products, substitute the given concentrations and time into the integrated rate law equation. After simplifying the equation, you will find the value of k to be approximately 0.012 M/min.
Step-by-step explanation:
To find the value of k for the zero-order reaction, we can use the integrated rate law for a zeroth-order reaction, which is given by [A] = [A]o - kt. In this case, the initial concentration of A is 0.970 M and it decreases to 0.209 M over a time of 63.5 minutes. We can substitute these values into the equation to solve for k:
0.209 M = 0.970 M - k(63.5 min)
Simplifying the equation, we get:
k = (0.970 M - 0.209 M) / 63.5 min
k = 0.761 M / 63.5 min
k = 0.01199 M/min, or approximately 0.012 M/min.