Answer:
Step-by-step explanation:
The equilibrium constant expression for the reaction system is given by:
Kc = [H₂S]² / ([H₂]²[S₂])
Using the given molar amounts, we can calculate the equilibrium concentrations of each species:
[H₂] = 0.5 mol / 1 L = 0.5 M
[S₂] = 0.02 mol / 1 L = 0.02 M
[H₂S] = 68.5 mol / 1 L = 68.5 M
Substituting these values into the equilibrium constant expression, we get:
Kc = (68.5)² / ((0.5)²(0.02))
Kc = 19658.75
Therefore, the equilibrium constant expression for the given reaction system is [H₂S]² / ([H₂]²[S₂]), and its numerical value is approximately 19658.75. Note that the units of Kc depend on the units of concentration used for each species.